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A 2-to-2′ 18-to-18′ doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad

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Abstract

The synthesis and properties of a 2-to-2′ 18-to-18′ doubly linked Ni(II) norcorrole dimer are described. It adopts a highly planar structure, resulting in effective electronic interactions between the constituent norcorrole units. Nevertheless, each norcorrole unit exhibits substantial antiaromaticity, which stands in sharp contrast to stacked norcorrole dimers.

Graphical abstract: A 2-to-2′ 18-to-18′ doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad

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Article information


Submitted
08 Apr 2020
Accepted
12 May 2020
First published
12 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A 2-to-2′ 18-to-18′ doubly linked Ni(II) norcorrole dimer: an effectively conjugated antiaromatic dyad

S. Liu, H. Kawashima, N. Fukui and H. Shinokubo, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02543G

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