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A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

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Abstract

The isolation, structural characterization and coordination chemistry of a di(amino)-substituted carbodiphosphorane (CDP) are reported. Compared to the analogue, dianionic bis(iminophosphoryl)methandiides, the CDP is a stronger C-, but much weaker N-donor which led to the isolation of solely C-coordinated metal complexes amongst an unusual monomeric trigonal-planar L·ZnCl2 complex.

Graphical abstract: A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

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Article information


Submitted
07 Apr 2020
Accepted
11 May 2020
First published
15 Jun 2020

This article is Open Access

Chem. Commun., 2020, Advance Article
Article type
Communication

A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

A. Kroll, H. Steinert, L. T. Scharf, T. Scherpf, B. Mallick and V. H. Gessner, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02496A

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