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Issue 53, 2020
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Constructing multi-cluster copper(i) halides using conformationally flexible ligands

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Abstract

Three unprecedented multi-cluster copper(I) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(I)-halide clusters in one system, which opens a new way for the construction of multi-Cu(I)-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.

Graphical abstract: Constructing multi-cluster copper(i) halides using conformationally flexible ligands

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Supplementary files

Article information


Submitted
06 Apr 2020
Accepted
23 May 2020
First published
26 May 2020

Chem. Commun., 2020,56, 7233-7236
Article type
Communication

Constructing multi-cluster copper(I) halides using conformationally flexible ligands

M. Yu, C. Liu, S. Li, Y. Zhao, J. Lv, Z. Zhuo, F. Jiang, L. Chen, Y. Yu and M. Hong, Chem. Commun., 2020, 56, 7233
DOI: 10.1039/D0CC02472D

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