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Coordination induced electron redistribution to achieve highly reversible Li-ion insertion chemistry in metal–organic frameworks

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Abstract

Herein, the coordination-induced increase in the electron density of fused C6 rings in MOFs as high performance anode materials for Li+ ion batteries is described. Zn-PTCA is able to deliver a high specific capacity of 700 mA h g−1 at 50 mA g−1 and exhibits excellent cycle performance over 1100 cycles and good rate capability.

Graphical abstract: Coordination induced electron redistribution to achieve highly reversible Li-ion insertion chemistry in metal–organic frameworks

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Article information


Submitted
06 Apr 2020
Accepted
29 Apr 2020
First published
29 Apr 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Coordination induced electron redistribution to achieve highly reversible Li-ion insertion chemistry in metal–organic frameworks

Z. Ye, Y. Liu, C. Fang, W. Chen, M. Ou, L. Li, X. Lin, Z. Rao, Y. Liao, R. Zhao, W. Chen and Y. Huang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02438D

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