Issue 59, 2020
From the journal:

Chemical Communications

The formation of a chiral supramolecular structure acting as a template for chirality transfer†

Misaki Kurataa  and  Atsushi Yoshizawa ORCID logo *a  

* Corresponding authors

a Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University, 3 Bunkyo-cho, Hirosaki, Aomori 036-8561, Japan
E-mail: ayoshiza@hirosaki-u.ac.jp

Abstract

Spontaneous mirror symmetry breaking in self-assembled achiral trimers under a nonequilibrium state induces supramolecular chirality, which is stabilized by a polymer network to produce a homochiral material. Chirality is transferred to the polymer film in the course of polymerization of achiral reactive monomers on the surface.

Graphical abstract: The formation of a chiral supramolecular structure acting as a template for chirality transfer

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Article information

DOI
https://doi.org/10.1039/D0CC02413A
Article type
Communication
Submitted
06 Apr 2020
Accepted
10 Jun 2020
First published
11 Jun 2020

Chem. Commun., 2020,56, 8289-8292

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The formation of a chiral supramolecular structure acting as a template for chirality transfer

M. Kurata and A. Yoshizawa, Chem. Commun., 2020, 56, 8289 DOI: 10.1039/D0CC02413A

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