Issue 50, 2020

A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

Abstract

The first trigonal bipyramidal Fe(II) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = −27.5 cm−1) and a pseudo-D3h symmetry at the Fe(II) centre, as investigated through ab initio and magnetic studies.

Graphical abstract: A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr 2020
Accepted
06 May 2020
First published
06 May 2020
This article is Open Access
Creative Commons BY license

Chem. Commun., 2020,56, 6826-6829

A large axial magnetic anisotropy in trigonal bipyramidal Fe(II)

M. A. Hay, A. Sarkar, G. A. Craig, K. E. R. Marriott, C. Wilson, G. Rajaraman and M. Murrie, Chem. Commun., 2020, 56, 6826 DOI: 10.1039/D0CC02382E

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