Issue 70, 2020

Dithioacetalization or thioetherification of benzyl alcohols using 9-mesityl-10-methylacridinium perchlorate photocatalyst

Abstract

We report herein the use of 9-mesityl-10-methylacridinium perchlorate as the visible-light photocatalyst for dithioacetalization or thioetherification of benzyl alcohols in one pot using aerial dioxygen as a terminal oxidant. EPR analysis and Stern–Volmer quenching studies helped to rationalize the single electron transfer (SET) mechanism.

Graphical abstract: Dithioacetalization or thioetherification of benzyl alcohols using 9-mesityl-10-methylacridinium perchlorate photocatalyst

Supplementary files

Article information

Article type
Communication
Submitted
01 Apr 2020
Accepted
22 Jul 2020
First published
23 Jul 2020

Chem. Commun., 2020,56, 10211-10214

Dithioacetalization or thioetherification of benzyl alcohols using 9-mesityl-10-methylacridinium perchlorate photocatalyst

M. Pramanik, K. Choudhuri, A. Mathuri and P. Mal, Chem. Commun., 2020, 56, 10211 DOI: 10.1039/D0CC02352C

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