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Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex

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Abstract

The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(II) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].

Graphical abstract: Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex

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Article information


Submitted
01 Apr 2020
Accepted
27 May 2020
First published
04 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(II) carbido complex

H. J. Barnett and A. F. Hill, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02349C

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