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Dehydroxyalkylative halogenation of C(aryl)–C bonds of aryl alcohols

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Abstract

We herein report Cu mediated side-directed dehydroxyalkylative halogenation of aryl alcohols. C(aryl)–C bonds of aryl alcohols were effectively cleaved, affording the corresponding aryl chlorides, bromides and iodides in excellent yields. Aryl alcohols could serve as both aromatic electrophilic and radical synthetic equivalents during the reaction.

Graphical abstract: Dehydroxyalkylative halogenation of C(aryl)–C bonds of aryl alcohols

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Article information


Submitted
30 Mar 2020
Accepted
19 May 2020
First published
19 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Dehydroxyalkylative halogenation of C(aryl)–C bonds of aryl alcohols

M. Liu, Z. Zhang, H. Liu, T. Wu and B. Han, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02306J

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