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Norbornadiene-bridged diarylethenes and their conversion into turn-off fluorescent photoswitches

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Abstract

We describe the synthesis and characterization of novel diarylethene photoswitches that contain a norbornadiene bridge and operate as p-type positive photochromes. One of the double bonds of norbornadiene is furthermore utilized to attach a fluoresceine tetrazine by an iEDDA cascade reaction, thereby forming a turn-off mode fluorescent photoswitch.

Graphical abstract: Norbornadiene-bridged diarylethenes and their conversion into turn-off fluorescent photoswitches

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Article information


Submitted
26 Mar 2020
Accepted
13 May 2020
First published
14 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Norbornadiene-bridged diarylethenes and their conversion into turn-off fluorescent photoswitches

S. M. Büllmann and A. Jäschke, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02210A

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