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Rotation of a helical coordination polymer by mechanical grinding

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Abstract

Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction in 83% yield.

Graphical abstract: Rotation of a helical coordination polymer by mechanical grinding

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Supplementary files

Article information


Submitted
24 Mar 2020
Accepted
30 Apr 2020
First published
07 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Rotation of a helical coordination polymer by mechanical grinding

B. B. Rath, G. K. Kole, S. A. Morris and J. J. Vittal, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02158J

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