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Issue 55, 2020
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Supramolecular organogel formation through three-dimensional α-cyclodextrin nanostructures: solvent chirality-selective organogel formation

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Abstract

Novel supramolecular organogels were efficiently formed by mixing a 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) solution of α-cyclodextrin (α-CD) with 1- or 2-butanol via the formation of three-dimensional hexagonal nanostructures composed of head-to-tail α-CD channel assemblies. Mixing (R)- and (S)-2-butanol with an α-CD/HFIP solution realized (S)-2-butanol-selective organogel formation.

Graphical abstract: Supramolecular organogel formation through three-dimensional α-cyclodextrin nanostructures: solvent chirality-selective organogel formation

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Supplementary files

Article information


Submitted
22 Mar 2020
Accepted
02 Jun 2020
First published
02 Jun 2020

Chem. Commun., 2020,56, 7581-7584
Article type
Communication

Supramolecular organogel formation through three-dimensional α-cyclodextrin nanostructures: solvent chirality-selective organogel formation

T. Kida, A. Teragaki, J. M. Kalaw and H. Shigemitsu, Chem. Commun., 2020, 56, 7581
DOI: 10.1039/D0CC02112A

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