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Issue 41, 2020
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Nitroprusside as a promising building block to assemble an organic–inorganic hybrid for thermo-responsive switching materials

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Abstract

We present a new hybrid compound, namely (Me2NH2)[KFe(CN)5(NO)], possessing a unique nitroprusside-based inorganic host framework in 4-connected sra topology encapsulating organic guest cations. The flexible host–guest hydrogen bonds and synchronously deformed inorganic framework give rise to thermal-responsive switching behaviours on both thermal expansion and nonlinear optical properties during the phase transition at around room temperature.

Graphical abstract: Nitroprusside as a promising building block to assemble an organic–inorganic hybrid for thermo-responsive switching materials

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Article information


Submitted
12 Mar 2020
Accepted
27 Mar 2020
First published
27 Mar 2020

Chem. Commun., 2020,56, 5488-5491
Article type
Communication

Nitroprusside as a promising building block to assemble an organic–inorganic hybrid for thermo-responsive switching materials

R. Qiu, X. Chen, R. Huang, D. Zhou, W. Xu, W. Zhang and X. Chen, Chem. Commun., 2020, 56, 5488
DOI: 10.1039/D0CC01877E

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