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Issue 45, 2020
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An inorganic–organic hybrid MnIII{Mn II6}2 cluster consisting of rare Lindqvist-like Mn6 subunits with high proton conductivity

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Abstract

A new inorganic–organic hybrid MnIII{MnII6}2 with rare Lindqvist-like Mn6 subunits was synthesized. Our studies reveal the distinct advantages of the MnIII{MnII6}2 compound as a potential material of proton exchange membranes, including its facile and cost-effective synthesis, insolubility in water, and most importantly, its maximum proton conductivity of 4.69 × 10−3 S cm−1 at 368 K and 97% RH.

Graphical abstract: An inorganic–organic hybrid MnIII{MnII6}2 cluster consisting of rare Lindqvist-like Mn6 subunits with high proton conductivity

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Article information


Submitted
10 Mar 2020
Accepted
21 Apr 2020
First published
21 Apr 2020

Chem. Commun., 2020,56, 6066-6069
Article type
Communication

An inorganic–organic hybrid MnIII{MnII6}2 cluster consisting of rare Lindqvist-like Mn6 subunits with high proton conductivity

S. Liu, Y. Deng and F. Xu, Chem. Commun., 2020, 56, 6066
DOI: 10.1039/D0CC01827A

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