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Recent advances in the sulfonylation reactions using potassium/sodium metabisulfite

Abstract

Recently, the sulfonylation reactions by using potassium/sodium metabisulfite as the sulfur dioxide surrogate have been developed rapidly. In most cases, the transformations go through radical processes with the insertion of sulfur dioxide under mild conditions. Additionally, transition metal catalysis is applied in the reactions for the synthesis of sulfonyl-containing compounds. Among the approaches, photoinduced conversions under visible light or ultraviolet irradiation are also involved. In this updated report, the insertion of sulfur dioxide from potassium metabisulfite or sodium metabisulfite is summarized.

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Article information


Submitted
07 Mar 2020
Accepted
24 Mar 2020
First published
24 Mar 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Feature Article

Recent advances in the sulfonylation reactions using potassium/sodium metabisulfite

S. Ye, M. Yang and J. Wu, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/D0CC01775B

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