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Recent advances in sulfonylation reactions using potassium/sodium metabisulfite

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Abstract

Recently, sulfonylation reactions using potassium/sodium metabisulfite as the sulfur dioxide surrogate have been developed rapidly. In most cases, the transformations go through radical processes with the insertion of sulfur dioxide under mild conditions. Additionally, transition metal catalysis is applied in the reactions for the synthesis of sulfonyl-containing compounds. Among the approaches, photoinduced conversions under visible light or ultraviolet irradiation are also involved. In this updated report, the insertion of sulfur dioxide from potassium metabisulfite or sodium metabisulfite is summarized.

Graphical abstract: Recent advances in sulfonylation reactions using potassium/sodium metabisulfite

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Article information


Submitted
07 Mar 2020
Accepted
24 Mar 2020
First published
24 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Feature Article

Recent advances in sulfonylation reactions using potassium/sodium metabisulfite

S. Ye, M. Yang and J. Wu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01775B

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