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Issue 38, 2020
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Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide

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Abstract

Borohydride (BH4)-containing coordination polymers converted CO2 into HCO2 or [BH3(OCHO)], whose reaction routes were affected by the electronegativity of metal ions and the coordination mode of BH4. The reactions were investigated using thermal gravimetric analysis under CO2 gas flow, infrared spectroscopy, and NMR experiments.

Graphical abstract: Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide

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Article information


Submitted
06 Mar 2020
Accepted
06 Apr 2020
First published
06 Apr 2020

Chem. Commun., 2020,56, 5111-5114
Article type
Communication

Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide

K. Kadota, E. Sivaniah and S. Horike, Chem. Commun., 2020, 56, 5111
DOI: 10.1039/D0CC01753A

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