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Issue 42, 2020
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A planar binuclear cobalt(ii) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan

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Abstract

This paper reports on a binuclear Co(II)Pc which exhibits a previously unknown extremely high catalytic activity for the oxidation of a thiol to the corresponding disulfide. The high activity is explained by an electronic contact between the two Co centres in the complex.

Graphical abstract: A planar binuclear cobalt(ii) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan

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Article information


Submitted
03 Mar 2020
Accepted
13 Apr 2020
First published
15 Apr 2020

Chem. Commun., 2020,56, 5653-5656
Article type
Communication

A planar binuclear cobalt(II) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan

S. G. Makarov, S. Yu. Ketkov and D. Wöhrle, Chem. Commun., 2020, 56, 5653
DOI: 10.1039/D0CC01653E

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