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Direct synthesis of 2-substituted benzonitriles via alkylcyanation of arynes with N,N-disubstituted aminomalononitriles

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Abstract

An efficient alkylcyanation of in situ generated arynes by N,N-disubstituted aminomalononitriles is described, enabling the direct synthesis of 2-substituted benzonitriles.

Graphical abstract: Direct synthesis of 2-substituted benzonitriles via alkylcyanation of arynes with N,N-disubstituted aminomalononitriles

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Article information


Submitted
29 Feb 2020
Accepted
22 May 2020
First published
25 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Direct synthesis of 2-substituted benzonitriles via alkylcyanation of arynes with N,N-disubstituted aminomalononitriles

W. Bao, Z. Gao, D. Jin, C. Xue, H. Liang, L. Lei, X. Xu, K. Zhang and S. Wang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01591A

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