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Issue 42, 2020
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Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage

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Abstract

A boronic ester cage, which exhibits stimuli-responsive guest-release behavior, was constructed by self-assembly of tetrol with the indacene backbone and a fluorine-substituted benzenetriboronic acid derivative. The presence of fluorine substituents made it possible to control the guest release rate using simple amines by forming tetrahedral borates.

Graphical abstract: Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage

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Article information


Submitted
24 Feb 2020
Accepted
07 Apr 2020
First published
08 Apr 2020

Chem. Commun., 2020,56, 5613-5616
Article type
Communication

Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage

H. Takata, K. Ono and N. Iwasawa, Chem. Commun., 2020, 56, 5613
DOI: 10.1039/D0CC01441A

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