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Unexpected persistence of cis-bridged chains in compressed AuF3

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Abstract

Raman scattering measurements indicate that cis-bridged chains are retained in AuF3 even at a compression of 45 GPa – in contrast to meta-GGA calculations suggesting that structures with such motifs are thermodynamically unstable above 4 GPa. This metastability implies that novel gold fluorides (e.g. AuF2) might be attainable at lower pressures than previously proposed.

Graphical abstract: Unexpected persistence of cis-bridged chains in compressed AuF3

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Article information


Submitted
21 Feb 2020
Accepted
24 Mar 2020
First published
24 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Unexpected persistence of cis-bridged chains in compressed AuF3

D. Kurzydłowski, S. Kobyakov, Z. Mazej, S. B. Pillai, B. Chakraborty and P. K. Jha, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01374A

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