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Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

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Abstract

Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-free N-formylation of amines with CO2 and hydrosilane to give formamides including Weinreb formamide, Me(MeO)NCHO, which was successively converted into aldehydes by one-pot reactions with Grignard reagents.

Graphical abstract: Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

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Article information


Submitted
21 Feb 2020
Accepted
14 Apr 2020
First published
15 Apr 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

T. Murata, M. Hiyoshi, M. Ratanasak, J. Hasegawa and T. Ema, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01371D

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