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Issue 43, 2020
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Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

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Abstract

Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-free N-formylation of amines with CO2 and hydrosilane to give formamides including Weinreb formamide, Me(MeO)NCHO, which was successively converted into aldehydes by one-pot reactions with Grignard reagents.

Graphical abstract: Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

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Article information


Submitted
21 Feb 2020
Accepted
14 Apr 2020
First published
15 Apr 2020

Chem. Commun., 2020,56, 5783-5786
Article type
Communication

Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

T. Murata, M. Hiyoshi, M. Ratanasak, J. Hasegawa and T. Ema, Chem. Commun., 2020, 56, 5783
DOI: 10.1039/D0CC01371D

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