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Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation

Abstract

The synthesis of novel tetrahydroquinoxalines by a metal induced one–electron reductive cyclisation of salophen ligands was found to occur when a salophen ligand was treated with chromium(II) chloride or decamethylcobaltocene

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Supplementary files

Article information


Submitted
14 Feb 2020
Accepted
25 Mar 2020
First published
25 Mar 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation

K. J. Lamb, M. Dowsett, M. North, R. R. Parker and A. C. Whitwood, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/D0CC01192D

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