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Stable metal–organic frameworks with low water affinity built from methyl-siloxane linkers

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Abstract

A tetracarboxylic acid with a methyl-substituted siloxane core (L-H4) has been prepared and applied in the construction of water stable MOFs with low water affinity. L-H4 itself crystallizes as an interpenetrated 3D hydrogen-bonded network. Reaction of L-H4 with ZrIV/HfIV gave IMP-32-Zr/Hf – both 3D MOFs of scu topology.

Graphical abstract: Stable metal–organic frameworks with low water affinity built from methyl-siloxane linkers

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Article information


Submitted
14 Feb 2020
Accepted
04 Jun 2020
First published
11 Jun 2020

This article is Open Access

Chem. Commun., 2020, Advance Article
Article type
Communication

Stable metal–organic frameworks with low water affinity built from methyl-siloxane linkers

L. C. Delmas, A. J. P. White, D. Pugh, A. Evans, M. A. Isbell, J. Y. Y. Heng, P. D. Lickiss and R. P. Davies, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01186J

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