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Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

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Abstract

Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.

Graphical abstract: Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

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Article information


Submitted
12 Feb 2020
Accepted
05 Mar 2020
First published
19 Mar 2020

This article is Open Access

Chem. Commun., 2020, Advance Article
Article type
Communication

Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

A. J. Bukvic, D. G. Crivoi, H. G. Garwood, A. I. McKay, T. T. D. Chen, A. J. Martínez-Martínez and A. S. Weller, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01140A

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