Jump to main content
Jump to site search


A novel approach for rhodium(iii)-catalyzed C–H functionalization of 2,2′-bipyridine derivatives with alkynes: a significant substituent effect

Author affiliations

Abstract

We described a novel approach for the C–H functionalization of 2,2′-bipyridine derivatives with alkynes. DFT calculations and experimental data showed a significant substituent effect at the 6-position of 2,2′-bipyridine, which weakened the adjacent N–Rh bond and provided the possibility of subsequent rollover cyclometalation, C–H activation, and functionalization.

Graphical abstract: A novel approach for rhodium(iii)-catalyzed C–H functionalization of 2,2′-bipyridine derivatives with alkynes: a significant substituent effect

Back to tab navigation

Supplementary files

Article information


Submitted
11 Feb 2020
Accepted
11 Mar 2020
First published
11 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A novel approach for rhodium(III)-catalyzed C–H functionalization of 2,2′-bipyridine derivatives with alkynes: a significant substituent effect

S. Wu, Z. Wang, Y. Bao, C. Chen, K. Liu and B. Zhu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01077D

Social activity

Search articles by author

Spotlight

Advertisements