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Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

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Abstract

A propeller-like pyrene derivative of diphenyl-1-pyrenylphosphine (DPPP) is designed and synthesized. DPPP exhibits a unique photo-triggered AIE/ACQ transition with a remarkable third-order nonlinear optical signal change, which is proved to originate from the photo-induced oxidation of a phosphorus atom.

Graphical abstract: Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

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Article information


Submitted
09 Feb 2020
Accepted
09 Mar 2020
First published
09 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

C. Xing, J. Liu, F. Chen, Y. Li, C. Lv, Q. Peng, H. Hou and K. Li, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01031F

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