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Ni–PC@SBA-15 derived from nano-sized Ni-MOF-74 confined in SBA-15 as a highly active catalyst for gas phase catalytic hydrodechlorination of 1,2-dichloroethane

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Abstract

A novel catalyst consisting of metallic Ni and porous carbon (PC) confined in SBA-15 was fabricated by the confined pyrolysis of nano-sized Ni-MOF-74 that was in situ grown in the mesopores of SBA-15. Due to the intimate contact between Ni and PC in a fine Ni–PC composite resulting from the confinement effect of mesoporous SBA-15, the catalyst displayed prominent catalytic activity and selectivity in the gas phase catalytic hydrodechlorination of 1,2-dichloroethane.

Graphical abstract: Ni–PC@SBA-15 derived from nano-sized Ni-MOF-74 confined in SBA-15 as a highly active catalyst for gas phase catalytic hydrodechlorination of 1,2-dichloroethane

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Article information


Submitted
07 Feb 2020
Accepted
13 May 2020
First published
14 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Ni–PC@SBA-15 derived from nano-sized Ni-MOF-74 confined in SBA-15 as a highly active catalyst for gas phase catalytic hydrodechlorination of 1,2-dichloroethane

X. Ning, D. Deng, H. Fu, X. Qu, Z. Xu and S. Zheng, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00998A

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