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Issue 33, 2020
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Spin-crossover in an organic–inorganic hybrid perovskite

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Abstract

The first spin-crossover (SCO) complex with an organic–inorganic hybrid perovskite structure (PPN)[Fe{Au(CN)2}3] (1) is reported, which displays three-step SCO behaviour. The light-induced excited spin-state trapping measurement gives T0 = 134 K for a three-dimensional FeL3-type (L = bis-monodentate ligand) SCO complex. Moreover, spin-state dependent fluorescence is observed in 1.

Graphical abstract: Spin-crossover in an organic–inorganic hybrid perovskite

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Supplementary files

Article information


Submitted
07 Feb 2020
Accepted
12 Mar 2020
First published
13 Mar 2020

Chem. Commun., 2020,56, 4551-4554
Article type
Communication

Spin-crossover in an organic–inorganic hybrid perovskite

W. Wu, S. Wu, Y. Chen, G. Huang, B. Lyu, Z. Ni and M. Tong, Chem. Commun., 2020, 56, 4551
DOI: 10.1039/D0CC00992J

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