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Issue 26, 2020
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Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand

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Abstract

An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state.

Graphical abstract: Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand

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Article information


Submitted
05 Feb 2020
Accepted
22 Feb 2020
First published
24 Feb 2020

Chem. Commun., 2020,56, 3733-3736
Article type
Communication

Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand

D. Shimoyama, R. Sekiya and T. Haino, Chem. Commun., 2020, 56, 3733
DOI: 10.1039/D0CC00933D

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