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Issue 54, 2020
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An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability

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Abstract

Rigid and topologically constrained ethylene cross-bridged tetraazamacrocycles have been increasingly utilised for thirty years as they form remarkably stable transition metal complexes for catalysis, biomedical imaging, and inorganic drug molecule applications. Extending these benefits to pentaazamacrocycles has been achieved and a first transition metal complex prepared and structurally characterized.

Graphical abstract: An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability

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Article information


Submitted
05 Feb 2020
Accepted
01 Jun 2020
First published
02 Jun 2020

Chem. Commun., 2020,56, 7519-7522
Article type
Communication

An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability

A. D. Shircliff, B. P. Burke, D. J. Davilla, G. E. Burgess, F. A. Okorocha, A. Shrestha, E. M. A. Allbritton, P. T. Nguyen, R. L. Lamar, D. G. Jones, M. Gorbet, M. B. Allen, J. I. Eze, A. T. Fernandez, D. Ramirez, S. J. Archibald, T. J. Prior, J. A. Krause, A. G. Oliver and T. J. Hubin, Chem. Commun., 2020, 56, 7519
DOI: 10.1039/D0CC00919A

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