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Issue 32, 2020
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A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction

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Abstract

The generation of a highly-substituted [2.2](2,5)pyrazinophane via a cascade reaction is presented. The pyrazinophane product is formed via the dimerization of a member of the para-azaquinodimethane (p-AQM) family of conjugated quinoidal compounds—reactivity that sheds light on the nature of stability in p-AQMs. Additionally, the electronic and structural nature of this highly-strained ring system are characterized.

Graphical abstract: A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction

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Article information


Submitted
04 Feb 2020
Accepted
09 Mar 2020
First published
10 Mar 2020

Chem. Commun., 2020,56, 4472-4475
Article type
Communication

A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction

C. L. Anderson, J. Liang, S. J. Teat, A. Garzón-Ruiz, D. P. Nenon, A. Navarro and Y. Liu, Chem. Commun., 2020, 56, 4472
DOI: 10.1039/D0CC00916D

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