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Issue 27, 2020
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High yielding self-assembly favored by preorganization

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Abstract

A series of macrocyclic molecules were self-assembled via imine condensation. In order to overcome the insolubility and lability of the amino precursors, amine deprotection and imine condensation are performed in a one-pot manner. Conformation preorganization of the precursors leads to high-yielding self-assembly of the cage products.

Graphical abstract: High yielding self-assembly favored by preorganization

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Article information


Submitted
04 Feb 2020
Accepted
29 Feb 2020
First published
02 Mar 2020

Chem. Commun., 2020,56, 3903-3906
Article type
Communication

High yielding self-assembly favored by preorganization

C. Zhang, T. Jiao, L. Tong, H. Wang, Y. Pan and H. Li, Chem. Commun., 2020, 56, 3903
DOI: 10.1039/D0CC00898B

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