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Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water

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Abstract

Visible-light-induced C–H phosphorylation of para-CAr–H and heteroarenes was realized using cost-effective RuCl3 as a catalyst. The reaction conditions are green and environmentally friendly, using water as a solvent at room temperature and without ligands. A broad range of highly functional organophosphorus compounds were obtained via a cross-dehydrogenation-coupling (CDC) reaction. In addition, we also proved that RuCl3 is a photocatalyst via its absorption spectrum and on/off light experiments.

Graphical abstract: Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water

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Article information


Submitted
16 Jan 2020
Accepted
16 Mar 2020
First published
18 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water

X. Gou, B. Zhang, X. Wang, W. Shi, H. Liu, Y. An, Z. Zhang and Y. Liang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00420K

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