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Bismuthanylstibanes

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Abstract

Thermally-robust bismuthanylstibanes are prepared in a one-step, high yield reaction, providing the first examples of neutral Bi–Sb σ-bonds in the solid state. DFT calculations indicate that the bis(silylamino)naphthalene scaffold is well-suited for supporting otherwise labile bonds. The reaction chemistry of the Bi–Sb bond is debuted by showing fission using NH3BH3 and insertion of a sulfur atom, the latter providing the first example of a Bi–S–Sb motif.

Graphical abstract: Bismuthanylstibanes

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Article information


Submitted
10 Jan 2020
Accepted
31 Jan 2020
First published
03 Feb 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Bismuthanylstibanes

K. M. Marczenko and S. S. Chitnis, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00254B

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