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Issue 58, 2020
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Bismuthanylstibanes

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Abstract

Thermally-robust bismuthanylstibanes are prepared in a one-step, high yield reaction, providing the first examples of neutral Bi–Sb σ-bonds in the solid state. DFT calculations indicate that the bis(silylamino)naphthalene scaffold is well-suited for supporting otherwise labile bonds. The reaction chemistry of the Bi–Sb bond is debuted by showing fission using NH3BH3 and insertion of a sulfur atom, the latter providing the first example of a Bi–S–Sb motif.

Graphical abstract: Bismuthanylstibanes

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Article information


Submitted
10 Jan 2020
Accepted
31 Jan 2020
First published
03 Feb 2020

Chem. Commun., 2020,56, 8015-8018
Article type
Communication

Bismuthanylstibanes

K. M. Marczenko and S. S. Chitnis, Chem. Commun., 2020, 56, 8015 DOI: 10.1039/D0CC00254B

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