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A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

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Abstract

For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.

Graphical abstract: A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

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Article information


Submitted
08 Jan 2020
Accepted
22 Apr 2020
First published
22 Apr 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

W. Zhang, J. Lin, P. Zhang and J. Xiao, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00188K

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