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Gold and Hypervalent Iodine(III) Reagents: Liaisons over a Decade for Electrophilic Functional Group Transfer Reactions

Abstract

Over the last two decades, hypervalent iodine(III) reagents have evolved from being ‘bonding curiosities’ to mainstream reagents in organic synthesis, in particular, electrophilic functional group transfer reactions. In this context, gold catalysis has not only emerged as a unique toolbox to facilitate such reactions (especially alkynylations) but also opened new possibilities with its different modes of reactivities for other functional group transfer reactions (acetoxylation and arylations). This feature article critically summarizes hitherto all such Au-catalyzed electrophilic functional group transfer reactions with hypervalent iodine(III) reagents, emphasizing on the mechanistic aspects.

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Article information


Submitted
06 Jan 2020
Accepted
06 Feb 2020
First published
06 Feb 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Feature Article

Gold and Hypervalent Iodine(III) Reagents: Liaisons over a Decade for Electrophilic Functional Group Transfer Reactions

N. Patil, S. BANERJEE and V. W. Bhoyare, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/D0CC00106F

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