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A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

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Abstract

Although the chemistry of frustrated Lewis pairs (FLPs) has seen tremendous developments, investigations on anionic, mono-molecular FLPs are still scarce and 1,3-zwitterions are unknown. Herein, synthesis of a K/OR phosphinidenoid complex bearing a Si–Cl function is reported and, hence, can serve as a synthetic equivalent for a 1,3-zwitterion to allow access to rare and novel heterocyclic P-ligands.

Graphical abstract: A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

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Article information


Submitted
02 Jan 2020
Accepted
26 Feb 2020
First published
06 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

R. Kunzmann, Y. Omatsu, G. Schnakenburg, A. Espinosa Ferao, T. Yanagisawa, N. Tokitoh and R. Streubel, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00024H

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