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Expedient iron-catalyzed stereospecific synthesis of triazines via cycloaddition of aziridines with diaziridines

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Abstract

Iron-catalyzed stereospecific [3+3]-annulation of aziridines with diaziridines is described to furnish [1,2,4]-triazines in high yield at room temperature. The use of an inexpensive iron salt catalyst, substrate scope and enantiomeric purity are the important practical features.

Graphical abstract: Expedient iron-catalyzed stereospecific synthesis of triazines via cycloaddition of aziridines with diaziridines

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Article information


Submitted
31 Dec 2019
Accepted
14 Feb 2020
First published
14 Feb 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Expedient iron-catalyzed stereospecific synthesis of triazines via cycloaddition of aziridines with diaziridines

T. Sarkar, K. Talukdar, S. Roy and T. Punniyamurthy, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC10089J

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