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Reactivity of Ce(iv) imido compounds with heteroallenes

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Abstract

The reactivity of alkali metal capped Ce(IV) imido compounds [M(DME)2][Ce[double bond, length as m-dash]NArF(TriNOx)] (1-M with M = K, Rb, Cs and ArF = 3,5-bis(trifluoromethyl)phenyl) with CO2 and organic isocyanates has been evaluated. 1-Cs reacted with CO2 to yield an organocarbamate complex. Reaction of 1-K and 1-Rb with organic isocyanates yielded organoureate Ce(IV) complexes.

Graphical abstract: Reactivity of Ce(iv) imido compounds with heteroallenes

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Article information


Submitted
06 Jan 2020
Accepted
29 Feb 2020
First published
02 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Reactivity of Ce(IV) imido compounds with heteroallenes

E. N. Lapsheva, T. Cheisson, C. Álvarez Lamsfus, P. J. Carroll, M. R. Gau, L. Maron and E. J. Schelter, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC10052K

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