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Issue 16, 2020
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A diarylethene annulated isomer as a highly-conductive molecular wire evaluated by the exchange interaction between two nitroxides

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Abstract

Bis(imino nitroxide) bridged by a diarylethene annulated isomer was synthesized and the exchange interaction between the two radicals was determined by the simulation of the ESR spectrum. The exchange interaction was found to be as large as that of the closed-ring isomer, suggesting that the annulated isomer can be used as a highly-conductive molecular wire in molecular electronics.

Graphical abstract: A diarylethene annulated isomer as a highly-conductive molecular wire evaluated by the exchange interaction between two nitroxides

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Article information


Submitted
27 Dec 2019
Accepted
20 Jan 2020
First published
20 Jan 2020

Chem. Commun., 2020,56, 2447-2450
Article type
Communication

A diarylethene annulated isomer as a highly-conductive molecular wire evaluated by the exchange interaction between two nitroxides

Y. Sumiya, K. Higashiguchi and K. Matsuda, Chem. Commun., 2020, 56, 2447
DOI: 10.1039/C9CC10017B

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