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Modular synthesis of (C-10 to C-13)-substituted-9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazines via a subsequent Buchwald–Hartwig amination and C–H amination strategy

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Abstract

Herein, we report a modular synthetic approach of (C-10 to C-13)-substituted 9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazine derivatives. This synthetic route enables the aromatic substitution in a predictable and programmed manner to obtain products in synthetically useful isolated yield.

Graphical abstract: Modular synthesis of (C-10 to C-13)-substituted-9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazines via a subsequent Buchwald–Hartwig amination and C–H amination strategy

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Submitted
26 Dec 2019
Accepted
16 Jan 2020
First published
17 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Modular synthesis of (C-10 to C-13)-substituted-9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazines via a subsequent Buchwald–Hartwig amination and C–H amination strategy

X. Li, C. Zhang, C. Wang, W. Ye, Q. Zhang, Z. Zhang, J. Su, Y. Chen and H. Tian, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09997B

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