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We report for the first time to our knowledge the identification of heteroatom-doped and undoped C3N4 with the energy-resolved distribution of electron traps (ERDT) near the conduction band bottom position (CBB) using reversed double-beam photoacoustic spectroscopy. The ERDT/CBB pattern is used to classify the type of elemental doping in C3N4, related to photocatalytic efficiency.

Graphical abstract: Energy-resolved distribution of electron traps for O/S-doped carbon nitrides by reversed double-beam photoacoustic spectroscopy and the photocatalytic reduction of Cr(vi)

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