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Interdigitated conducting tetrathiafulvalene-based coordination networks

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Abstract

Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10−6 vs. 10−12 S cm−1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.

Graphical abstract: Interdigitated conducting tetrathiafulvalene-based coordination networks

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Article information


Submitted
24 Dec 2019
Accepted
21 Jan 2020
First published
24 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Interdigitated conducting tetrathiafulvalene-based coordination networks

D. Bechu, L. S. Xie, N. Le Breton, S. Choua, M. Dincă, M. W. Hosseini and S. A. Baudron, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09960C

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