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Issue 54, 2020
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Copper-catalyzed borylamidation of vinyl arenes with isocyanates

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Abstract

A copper-catalyzed borylative amidation of vinyl arenes with isocyanates and bis(pinacolato)diboron has been developed. This new protocol, which can be performed on a gram-scale, utilizes isocyanates as simple precursors to provide access to a range of boryl alkyl amides. The products contain valuable amide and boronate, which are amenable for further elaboration, and have versatile synthetic utilities.

Graphical abstract: Copper-catalyzed borylamidation of vinyl arenes with isocyanates

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Article information


Submitted
23 Dec 2019
Accepted
26 May 2020
First published
27 May 2020

Chem. Commun., 2020,56, 7483-7486
Article type
Communication

Copper-catalyzed borylamidation of vinyl arenes with isocyanates

Z. Su, Y. Feng, R. Zou, X. Qiu, J. Wang and C. Tao, Chem. Commun., 2020, 56, 7483
DOI: 10.1039/C9CC09902F

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