Pressure-induced inclusion of neon in the crystal structure of a molecular Cu2(pacman) complex at 4.67 GPa

Nico Giordano; Christine M. Beavers; Konstantin V. Kamenev; Jason B. Love; James R. Pankhurst; Simon J. Teat; Simon Parsons

doi:10.1039/C9CC09884D

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Pressure-induced inclusion of neon in the crystal structure of a molecular Cu₂(pacman) complex at 4.67 GPa†

Nico Giordano,

‡^ab Christine M. Beavers,

§^bc Konstantin V. Kamenev,

^d Jason B. Love,

^a James R. Pankhurst,

^a Simon J. Teat

^b and Simon Parsons

*^a

Author affiliations

* Corresponding authors

^a EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh, King's Buildings, W. Mains Rd, Edinburgh, UK
E-mail: simon.parsons@ed.ac.uk

^b Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720-8229, USA

^c Department of Earth & Planetary Sciences, University of California, Santa Cruz, 1156 High Street, Santa Cruz, CA 95064, USA

^d Centre for Science at Extreme Conditions and School of Engineering, The University of Edinburgh, King's Buildings, West Mains Road, Edinburgh, Scotland, UK

Abstract

Crystals of a Cu complex of the macrocyclic Schiff-base calixpyrrole or ‘Pacman’ ligand, Cu₂(L), do not contain any solvent-accessible void space at ambient pressure, but adsorb neon at 4.67 GPa, forming Cu₂(L)·3.5Ne.

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Article information

DOI: https://doi.org/10.1039/C9CC09884D
Article type: Communication
Submitted: 20 Dec 2019
Accepted: 17 Feb 2020
First published: 17 Feb 2020
This article is Open Access

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Chem. Commun., 2020,56, 3449-3452

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Pressure-induced inclusion of neon in the crystal structure of a molecular Cu₂(pacman) complex at 4.67 GPa

N. Giordano, C. M. Beavers, K. V. Kamenev, J. B. Love, J. R. Pankhurst, S. J. Teat and S. Parsons, Chem. Commun., 2020, 56, 3449 DOI: 10.1039/C9CC09884D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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