Issue 39, 2020

One-dimensional co-crystallized coordination polymers showing reversible mechanochromic luminescence: cation–anion interaction directed rapid self-recovery

Abstract

Three one-dimensional (1D) chain polymers (1D-9HAC, 1D-Cd-9AC, and 1D-Cd-9AC–HBIM) that exhibit different intermolecular interactions and stacking patterns have been designed and synthesized. Only 1D-Cd-9AC–HBIM with rigid (anion) and flexible (cation) units alternately arranged exhibits mechanochromic luminescence, which can be recovered through rapid solvent treatment or a self-recovery process.

Graphical abstract: One-dimensional co-crystallized coordination polymers showing reversible mechanochromic luminescence: cation–anion interaction directed rapid self-recovery

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2019
Accepted
25 Mar 2020
First published
25 Mar 2020

Chem. Commun., 2020,56, 5267-5270

One-dimensional co-crystallized coordination polymers showing reversible mechanochromic luminescence: cation–anion interaction directed rapid self-recovery

Y. Yang, X. Fang, S. Zhao, F. Bai, Z. Zhao, K. Wang and D. Yan, Chem. Commun., 2020, 56, 5267 DOI: 10.1039/C9CC09806B

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