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Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C–H halogenation

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Abstract

In this work, we report the first use of a salen-based hypercrosslinked polymer-supported Pd catalyst to carry out C–H halogenation. This catalyst can effectively catalyze C–H bromination and chlorination even better than its homogeneous counterpart Pd(OAc)2. It also showed excellent reusability without loss of catalytic activity for ten cycles. A broad substrate scope was explored and moderate to excellent yields were obtained.

Graphical abstract: Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C–H halogenation

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Article information


Submitted
17 Dec 2019
Accepted
30 Jan 2020
First published
30 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C–H halogenation

D. Meng, J. Bi, Y. Dong, B. Hao, K. Qin, T. Li and D. Zhu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09781C

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